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Meteorite Fusion Crust
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An illustrated introduction
In-flight Spalling
There is another feature common with fusion crusts
that is rarely addressed in the literature. Particularly
those meteorites with a very thick fusion crust of 1 mm or
more often display blank patches bare of crust. The CV3 chondrite
Allende is a well-known example. These bare patches often appear
on protrusions and flanks of a specimen, but they occur on flat
surfaces as well. The flaking is not a result of the meteorite’s
impact. In fact, most of the spalling happens in flight. Other
evidence for spalling of fusion crust during the flight of a meteoroid
are areas free of crust that bear traces of sooting, a good sign that
the spalling occurred during the final stage of the hot flight.
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Characteristic signs of in-flight spalling on a Thuathe H4/5 chondrite. Note that most bare patches occur on edges or rims
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Depending on the meteroid’s surface shape, its heat
conductivity, the thickness of the fusion crust, the composition
and grain size of the underlying mineral matrix and the temperature
gradient the meteroid encounters during its fall, the adhesion with
which the fusion crust sticks to the meteorite varies. Thus, it occurs that
patches of crust are stripped from the meteoroid through
atmospheric drag in the air stream. As Ramdohr (1967) pointed out, the thin magnetite
fusion crust of irons is particularly susceptible to in-flight spalling.
Surface Weathering
Finally, our meteoroid hits the ground and thus becomes
what is called a meteorite. Often the fusion crust is damaged
by the impact. Bare patches or adhering soil material will be
future starting points for weathering. Depending on the hardness
of the target surface and due to the low impact velocities it is
as well possible that the fusion crusts survives intact. Of the
large meteorite falls Pultusk, Mocs, Millbillillie, Camel Donga, Gao,
Bassikounou and Chergach for example, many specimens are
known displaying no chips at all.
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Moderately weathered LL6-chondrite (Al Mahbes). The crust
free surfaces show developing patina and traces of sand abrasion. Clay minerals have
settled in the contraction cracks.
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Once fallen onto the earth’s surface, the fusion crust
protects the meteorite from the effects of terrestrial weathering.
Simultaneously, it is the most exposed part of a crusted meteorite,
and a very vulnerable part, in fact.
If one inspects the fusion crust of a stone meteorite recovered
hours or days after its fall, one will find a disturbed, coarse
and tubercular texture that provides the meteorite with an increased
surface for the attacks of chemical and mechanical weathering. The
rough fusion texture tends to bond contaminants like calcium carbonates,
clay particles, aggregates of wind-born dust and dew. Despite its
relative hardness, its lack of compactness makes it easy prey to
abrasion through wind-borne ice crystals or saltating
sand grains.
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Rear surface of the Al Mahbes LL6 chondrite pictured above. Corrasion has carved out
deep grooves and is working its way further into the meteorite. The
remaining fusion crust shows a shimmering luster, a result of progressed sand polishing
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Corrasion
Besides oxidation, one of the first visible effects of weathering
on a meteorite in arid environments with abundant quartz sand is a light
polish or luster caused by saltation. The continuous impact of quartz grains
erodes the outer vesicular layer of the fusion crust. While the underlying
substrate is still in place, the thin, rough-textured upper layer is abraded
to a certain extent by wind-borne sand. A process also known as corrasion. In areas with
abundance of quartz sand, this effect can occur after only few months.
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Fusion crust stripped off by corrasion on the olivine diogenite NWA 5597
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Meteorites in cold environments are susceptible to a similarly quick method of
erosion. Despite their often long terrestrial residence, many Antarctic finds display
quite fresh interiors while their exterior is heavily abraded by wind-borne ice crystals
up to depths of 1 cm and more. Once the fusion crust is gone in places, the developing bare patches function
as access gates for eroding particles. Often the meteorite’s matrix is deeply
carved out between and even under patches of intact fusion by impacting ice crystals
or quartz grains.
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Rust flowering on the fusion crust of an L5 chondrite from the SAU 001 strewn field |
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Further Mechanical and Chemical Attacks
The temperature gradient at the meteorite’s resting place is
another important factor for the preservation of fusion crust.
Large gaps between day and night temperature peaks will increase
shear stress between the interior of the meteorite and its fusion
crust because each has a different coefficient of expansion and
contraction. Eventually, the induced shear stress leads to further
flaking of the crust.
At the same time, the fusion crust is subjected to chemical
attacks both from the outside and the inside. The main chemical
weathering reactions taking place in a meteorite exposed to the elements
are oxidation, hydration and solution.
Humidity penetrates the meteorite
through cracks and fractures. The humidity will dissolve available chlorides
(in exchange for OH) and distribute them through the meteorite. Developing
Fe(II) chloride (FeCl2) oxidizes further to Fe(III) chloride (FeCl3) and
together with water it forms hydrochloric acid which is attacking the meteorite
even further. The oxidation
of the meteorite’s iron is locally expanding its volume. If this occurs
near its surface this will result in flaking of the fusion crust.
While the iron in the meteorite is oxidized to new weathering
minerals such as goethite, minerals like olivine, pyroxene and feldspar
turn into claylike combinations. While olivine is most susceptible
to alteration feldspar offers the most lasting resistance. In a progressed state (W2-W3)
these effects result in a rather brown color on the meteorite’s interior and exterior.
Sometimes, as with many finds from the deserts in Oman,
leaching of dissolved oxides occurs which results
in growing rust deposits on the exterior.
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Large weathering crack emerging on the surface of a heavily sandpolished polymict ureilite (name and publication pending)
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Weathering Cracks
If exposed on the surface for a long time, meteorites
often develop deep weathering cracks. Contrary to contraction
cracks, these are intersecting the meteorite’s interior,
providing further access to moisture and dissolving agents and
thus contributing to an even quicker alteration of the meteorite’s
lithology. Sooner or later, these cracks will result in the complete
fragmentation of the exposed mass.
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